SHELL OIL CO -- 94012, SHELLZONE ANTIFREEZE  -- 6850-00N033509
<pre>=====================  Product Identification  =====================

Product ID:94012, SHELLZONE ANTIFREEZE
MSDS Date:06/28/1989
FSC:6850
NIIN:00N033509
=== Responsible Party ===
Company Name:SHELL OIL CO
Box:4320
City:HOUSTON
State:TX
ZIP:77210
Country:US
Info Phone Num:713-241-4819
Emergency Phone Num:713-473-9461;800-424-9300(CHEMTREC)
Preparer's Name:G.A. VAN GELDER
CAGE:SHELO
=== Contractor Identification ===
Company Name:SHELL OIL CO
Box:4320
City:HOUSTON
State:TX
ZIP:77210-5000
Country:US
Phone:713-473-9461/713-241-2252
CAGE:SHELO
Company Name:SHELL OIL COMPANY
Address:Box:2463
City:HOUSTON
State:TX
ZIP:77210
Country:US
Phone:800-231-6950
CAGE:54527

=============  Composition/Information on Ingredients  =============

Ingred Name:SPILL PROC:SALVAGE VESSELS. SOAK UP RESIDUE W/ABSORB SUCH
    AS CLAY, SAND/OTHER SUITABLE MATL; DISP OF PROPERLY. (ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12:FLUSH AREA W/H*2O TO REMOVE TRACE RESIDUE. SM
    SPILLS:TAKE UP W/ABSORB MATL & DISP OF PROPERLY. KEEP OUT (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13:OF SURF WATERS, SEWERS & WATERWAYS ENTERING/LEADING
    TO SURF WATERS. NOTIFY AUTHS IF ANY EXPOS TO GENERAL (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14:PUBLIC OR ENVIRONMENT OCCURS OR IS LIKELY TO OCCUR.
RTECS #:9999999ZZ

Ingred Name:ETHYLENE GLYCOL  (SARA III). LD50:(ORAL,RAT)4 G/KG.
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 84-94%
OSHA PEL:50 PPM, C
ACGIH TLV:50 PPM, C
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Ingred Name:DIETHYLENE GLYCOL. LD50:(ORAL,RAT)14.8 G/KG.
CAS:111-46-6
RTECS #:ID5950000
Fraction by Wt: 0-10%

Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 2-4%

Ingred Name:SALTS; (INORGANIC/ORGANIC SALTS)
Fraction by Wt: 2-4%

Ingred Name:SUPDAT:1 WAS ADMIN BY GAVAGE @ DAILY DOSES OF 1.25 G/KG &
    ABOVE TO PREGNANT RATS/@ 750 MG/KG & ABOVE TO PREGNANT (ING 6)
RTECS #:9999999ZZ

Ingred Name:ING 5:MICE, THERE WAS INCR IN NUMBER OF MALFORMED FETUSES @
    ALL DOSE LEVELS. EXCEPT @ LOWEST DOSE LEVEL IN MICE, (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6:THERE WAS ALSO EVID OF MATERNAL TOXICITY AT ALL DOSE
    LEVELS.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC:2 GLASSES OF H*2O & INDUCE VOMIT BY TOUCHING
    FINGER TO BACK OF VICTIM'S THROAT. KEEP VICTIM'S HEAD(ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8:BELOW HIPS WHILE VOMIT. GET MD. NOTE TO MD:IF VICTIM
    IS CHILD, GIVE NO MORE THAN 1 GLASS OF H*2O & 15CC (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9:(1 TBSP) SYRUP OF IPECAC. IF SYMPS SUCH AS LOSS OF
    GAG REFLEX, CONVLS/UNCON OCCUR BEFORE EMESIS, GASTRIC (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10:LAVAGE SHOULD BE CONSIDERED FOLLOWING INTUBATION
    W/CUFFED ENDOTRACHEAL TUBE.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:SEE INGREDIENTS 1 & 2.
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:EYE:ING 1:MOD TO SEV IRRIT. VAPS CAN
    ALSO CAUSE SEV IRRIT. SKIN:INGS 1 & 2:MILDLY IRRIT & SLIGHTLY TOX
    ON PRLNG/RPTD CONT. INHAL:VAPS ARE MILDLY TO MARKEDLY IRRIT TO
    LUNGS DEPENDING ON EXPOS LEVELS. I NGEST:PROD MAY BE HARMFUL/FATAL
    IF SWALLOWED; MAY PRDCE CNS DEPRESS & KIDNEY DMG WHICH MAY BE
    FATAL. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INGEST OF ING 2 MAY ALSO PRDCE LIVER
    DMG. SIGNS & SYMPS:IRRIT AS NOTED. EARLY TO MOD CNS DEPRESS MAY BE
    EVID BY GIDD, HDCH, DIZZ & NAUS; IN EXTREME CASES, UNCON & DEATH
    MAY OCCUR. KIDNEY DMG  MAY BE EVID BY CHANGES IN URINE OUTPUT,URINE
    APPEAR/EDEMA (SWELL FROM FLUID RETENTION). LIVER DMG MAY BE EVID
    (SUPDAT)
Medical Cond Aggravated by Exposure:PREEXISTING SKIN, EYE & RESP
    DISORDERS MAY BE AGGRAVATED BY EXPOS TO PROD. IMPAIRED KIDNEY &
    LIVER FUNCTIONS FROM PREEXISTING DISORDERS MAY BE AGGRAVATED BY
    EXPOS TO PROD.

=======================  First Aid Measures  =======================

First Aid:EYE:IMMED FLUSH W/PLENTY OF H*2O FOR @ LST 15 MINS WHILE
    HOLDING EYELIDS OPEN. GET MD. SKIN:FLUSH W/H*2O. IF IRRIT OCCURS,
    GET MD. INHAL:REMOVE VICTIM TO FRESH AIR & PROVIDE O*2 IF BRTHG IS
    DFCLT. GET	MD. INGEST:DO NOT GIVE LIQS IF VICTIM IS UNCON/VERY
    DROWSY. OTHERWISE, GIVE NO MORE THAN 2 GLASSES OF H*2O & INDUCE
    VOMIT BY GIVING 30CC (2 TBSPS) SYRUP OF IPECAC. IF IPECAC IS
    UNAVAIL, GIVE (ING 8)

=====================  Fire Fighting Measures  =====================

Flash Point Method:SCC
Flash Point:246F,119C
Extinguishing Media:USE WATER FOG, "ALCOHOL" FOAM, DRY CHEMICAL OR
    CO*2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
    PROTECTIVE EQUIPMENT . MATERIAL WILL NOT BURN UNLESS PREHEATED.
    COOL FIRE EXPOSED CONTAINERS W/WATER.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

==================  Accidental Release Measures  ==================

Spill Release Procedures:MAY BURN ALTHOUGH NOT READILY IGNITABLE. USE
    CAUT JUDGMENT WHEN CLEANING UP LG SPILLS. LG SPILLS:WEAR NIOSH/MSHA
    APPRVD RESP & PROT CLTHG AS APPROP. SHUT OFF SOURCE OF LEAK IF SAFE
    TO DO SO. DIKE & CO NTAIN. REMOVE W/VACUUM TRUCK/PUMP TO STOR/(ING
    12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:AVOID CONTACT W/EYES. AVOID
    PROLONGED/REPEATED CONTACT W/SKIN. STORE IN A COOL, DRY PLACE
    W/ADEQUATE VENTILATION.
Other Precautions:KEEP AWAY FROM FLAMES & HIGH TEMPERATURES.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF EXPOS MAY/DOES EXCEED OCCUP EXPOS LIMITS USE
    A NIOSH/MSHA APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. I/A/W 29
    CFR 1910.134 USE EITHER NIOSH/MSHA APPROVED ATMOSPHERE-SUPPLYING
    RESPIRATOR OR AIR-PU RIFYING RESPIRATOR FOR ORGANIC VAPORS.
Ventilation:USE VENTILATION AS REQUIRED TO CONTROL VAPOR
    CONCENTRATIONS.
Protective Gloves:NITRILE, NEOPRENE, PVC/NATRL RUB GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:CHEM RESISTANT CLTHG AS REQD TO MIN CONT.
    EYE WASH FOUNTAINS & SAFETY SHOWERS SHOULD BE AVAIL FOR EMERGENCY
    USE.
Work Hygienic Practices:WASH W/SOAP & H*2O BEFORE EATING, DRINKING,
    SMOKING/USING TOILET FACILITIES. LAUNDER CONTAM CLTHG BEFORE REUSE.
Supplemental Safety and Health
EFTS OF OVEREXP:BY LOSS OF APPETITE, JAUNDICE (YELLOWISH SKIN COLOR) &
    SOMETIMES PAIN IN UPPER ABDOMEN ON RIGHT SIDE. INTENT ABUSE,
    MISUSE/OTHER MASSIVE EXPOS MAY CAUSE MULTIPLE ORGAN DMG &/OR DEATH.
     RARE CASES OF ING 1 SENSIT (ALLERGY) HAVE BEEN PUBLISHED BUT
    ALLERGY TO ING 1 IS NOT COMMON PHENOMENON. WHEN ING (ING 5)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:>330F,>166C
Vapor Density:>1
Spec Gravity:1.373 (H*2O=1)
Evaporation Rate &amp; Reference:<0.01 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:BLUE GREEN, SLIGHTLY VISCOUS LIQUID; MILD ODOR.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
KEEP AWAY FROM STRONG OXIDIZING MATERIALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CO & UNIDENTIFIED ORGANIC COMPOUNDS
    MAY BE FORMED DURING COMBUSTION.

====================  Disposal Considerations  ====================

Waste Disposal Methods:PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN
    COMPLIANCE W/LOCAL, STATE & FEDERAL REGULATIONS.

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